Compilation - 1,2,3-Trichloropropane with Water (IUPAC SDS Volume 68)
SDS Volume (3571)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Room Temp: 275 - 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
5 μL 1,2,3-trichloropropane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,2,3-trichloropropane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
- Source and purity not given.
- distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±6.1%.
Components:
- 1,2,3-Trichloropropane, $\ce{ C3H5Cl3 }$; [96-18-4] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 1.9 | 7.230 | 8.841 x 10-5 | 11.66 |
| 13.5 | 16.51 | 2.021 x 10-4 | 11.46 |
| 15.7 | 15.96 | 1.953 x 10-4 | 13.55 |
| 17.1 | 16.83 | 2.060 x 10-4 | 14.18 |
| 22 | 21.73 | 2.661 x 10-4 | 15.12 |
| 24.9 | 20.0 | 2.448 x 10-4 | 19.81 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
(b) These values were calculated by the compiler.
