SDS Volume (3531)

Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None

Original Measurements

Miller, M. M.; Wasik, S. P.; Huang, G. L.; Shiu, W. Y.; Mackay, D.; Environ. Sci. Technol. 1985, 19, 522-529.

Variables:

Room Temp: 298 $\pu{K}$

Prepared by:

A.L. Horvath

Method/Apparatus/Procedure:

A saturated aqueous solution was prepared by passing of water through a column which was packed with glass beads coated with 1-bromoheptane. The saturated solution was then pumped through an extractor column and 1-bromoheptane was extracted directly into an analytical column. The samples were analyzed with a liquid chromatograph equipped with both an UV ab-sorbance and a fluorescence detector with excitation filters. The peak area was established using a Hewlett-Packard recorder.

Source and Purity of Materials:
  1. Eastman Kodak Company. Commercial quality, used as received.
  2. Double distilled.
Estimated Errors:

Ambient temperature: ±1.0 K (compiler).
Mass concentration (m/v) (1): Not specified.

Components:
  1. 1-Bromoheptane, $\ce{ C7H15Br }$; [629-04-9] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) $C_{1}$ (mol/m3) 100w1 $x_{1}$
25 0.0371 6.68 x 10-46.72 x 10-7

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