Compilation - 1-Bromoheptane with Water (IUPAC SDS Volume 68)
SDS Volume (3530)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Tewari, Y. B.; Miller, M. M.; Wasik, S. P.; Martire, D. E.; J. Chem. Eng. Data 1982, 27, 451-4.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The modified generator column method was used. A chromatographic column was coated with liquid 1-bromoheptane. An aqueous phase was generated by pumping water through the coated generator column. The aqueous solution was analyzed by a gas chromatographic method using a gas chromatograph equipped with a flame ionization detector. The result is the average of at least three measurements.
Source and Purity of Materials:
- Source not given. At least 99% pure by GC analysis.
- Baker-analysed HPLC grade.
Estimated Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±1.0%.
Components:
- 1-Bromoheptane, $\ce{ C7H15Br }$; [629-04-9] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $C_{1}$ (mol/dm3) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 25 | 3.71 x 10-5 | 6.68 x 10-4 | 6.72 x 10-7 |
