SDS Volume
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Source Publication
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Conditions:
Room Temp: 274 - 296 $\pu{K}$
Compiler:
Methodology:
A 5 μL 1-chlorohexane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1-chlorohexane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Sample Information:
- Source and purity not given.
- distilled.
Measurement Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±5.8%.
System Components:
- 1-Chlorohexane, $\ce{ C6H13C1 }$; [544-10-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 a | $x_{1}$ a | DL |
|---|---|---|---|
| 1 | 3.687 x 10-3 | 5.507 x 10-6 | 399.5 |
| 3 | 4.946 x 10-3 | 7.387 x 10-6 | 365.5 |
| 12.4 | 5.645 x 10-3 | 8.432 x 10-6 | 668.3 |
| 12.5 | 5.248 x 10-3 | 7.839 x 10-6 | 728.4 |
| 17.9 | 6.187 x 10-3 | 9.241 x 10-6 | 873.2 |
| 19.1 | 5.929 x 10-3 | 8.855 x 10-6 | 969.7 |
| 22.7 | 6.237 x 10-3 | 9.316 x 10-6 | 1.1614 x 103 |
| 23.0 | 5.783 x 10-3 | 8.638 x 10-6 | 1.2677 x 103 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
