Compilation - 1,5-Dichloropentane with Water (IUPAC SDS Volume 68)
SDS Volume (3488)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Room Temp: 274 - 296 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A 5 μL 1,5-dichloropentane sample was in-jected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,5-dichloropentane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
- Source and purity not given.
- distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±12.9%.
Components:
- 1,5-Dichloropentane, $\ce{ C5H10Cl2 }$; [628-76-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 1.0 | 0.01170 | 1.4949 x 10-5 | 16.36 |
| 3.0 | 9.763 x 10-3 | 1.2472 x 10-5 | 23.10 |
| 12.04 | 0.02214 | 2.8282 x 10-5 | 21.41 |
| 12.5 | 0.01642 | 2.0974 x 10-5 | 28.87 |
| 17.9 | 0.02635 | 3.3668 x 10-5 | 26.96 |
| 19.1 | 0.02080 | 2.6579 x 10-5 | 36.69 |
| 22.7 | 0.01232 | 1.5732 x 10-5 | 79.33 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
(b) These values were calculated by the compiler.
