Compilation - 1-Chlorobutane with Water (IUPAC SDS Volume 68)
SDS Volume (3466)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Room Temp: 274 - 296 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A 5 μL 1-chlorobutane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1-chlorobutane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
- Source and purity not given.
- distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±2.1%.
Components:
- 1-Chlorobutane, $\ce{ C4H9C1 }$; [109-69-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 1.0 | 0.06241 | 1.2153 x 10-4 | 325.5 |
| 3.0 | 0.06050 | 1.1780 x 10-4 | 375.3 |
| 12.4 | 0.06992 | 1.3616 x 10-4 | 536.9 |
| 12.5 | 0.06596 | 1.2843 x 10-4 | 569.2 |
| 17.9 | 0.07115 | 1.3855 x 10-4 | 693.4 |
| 19.1 | 0.07014 | 1.3659 x 10-4 | 738.2 |
| 22.7 | 0.07331 | 1.4276 x 10-4 | 833.9 |
| 23.0 | 0.07458 | 1.4524 x 10-4 | 839.0 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
(b) These values were calculated by the compiler.
