Compilation - 1-Chlorobutane with Water (IUPAC SDS Volume 68)
SDS Volume (3465)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Sato, A.; Nakijima, T.; Arch. Envir. Health 1979, 34, 69-75.
Variables:
Room Temp: 310 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
1-Chlorobutane vapor was equilibrated in an airtight vial between water and the overlying air. When equilibrium was established, a portion of the equilibrated air in the vessel was withdrawn using an airtight syringe and was injected into a gas chromatograph and analyzed. The peak height of the chromatogram was used to calculate the partition coefficient.
Source and Purity of Materials:
- Source and purity not given.
- Distilled.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): ±0.18 std. dev.
Components:
- 1-Chlorobutane, $\ce{ C4H9C1 }$; [109-69-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 37 | 0.0711 | 1.385 x 10-4 | 0.86 |
(a) Gas-liquid partition parameter, from instrument calibration.
