Compilation - 1,4-Dichlorobutane with Water (IUPAC SDS Volume 68)
SDS Volume (3450)
Volume 68. Halogenated Aliphatic Compounds C3-C14 with Water, p None
Original Measurements
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Room Temp: 287 - 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A 5 μL 1,4-Dichlorobutane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,4-Dichlorobutane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
- Source and purity not given.
- distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±6.1%.
Components:
- 1,4-Dichlorobutane, $\ce{ C4H8C12 }$; [110-56-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 13.5 | 0.1201 | 1.705 x 10-4 | 15.27 |
| 15.7 | 0.1044 | 1.482 x 10-4 | 20.05 |
| 17.1 | 0.1082 | 1.536 x 10-4 | 21.35 |
| 22.0 | 0.1283 | 1.822 x 10-4 | 24.76 |
| 24.9 | 0.1574 | 2.236 x 10-4 | 26.61 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
