SDS Volume (3424)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 456
Original Measurements
Sedmerova, V.; Novak, J. P.; Chem. Prum. 16, 270 (1966).
Variables:
Room Temp: 293 - 313 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The titration method was used. Water was titrated with trichloroethene from a burette. The mixture was kept at constant temperature under vigorous stirring until the appearance of turbidity.
Source and Purity of Materials:
- Source not given, technical grade, distilled and dried over $\ce{CaCl2}$ before use, BP = 87.20°C, $d^{20}$ = 1.4662.
- Twice distilled.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Components:
- Trichloroethylene, $\ce{ C2HCl3 }$; [79-01-6] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | 100w2 | $x_{1}$ | $x_{2}$ |
|---|---|---|---|---|
| 19.85 | 1.0 x 10-3 | 7.0 x 10-4 | 1.4 x 10-6 | 5.0 x 10-5 |
| 29.85 | 1.5 x 10-3 | 1.0 x 10-3 | 2.1 x 10-6 | 7.0 x 10-5 |
| 39.85 | 2.0 x 10-3 | 1.2 x 10-3 | 2.7 x 10-6 | 8.7 x 10-5 |
