SDS Volume
Volume 67. Halogenated Ethanes and Ethenes with Water, p 453
Source Publication
Powell, J. F.; Br. J. Industr. Med. 4, 233 (1947).
Conditions:
Room Temp: 293 - 310 $\pu{K}$
Compiler:
Methodology:
The trichloroethene and air mixtures were prepared in gas cylinders under pressure. An Oxford vaporizer was used to produce a high concentration of trichloroethene. Water was equilibrated with the gas mixture by a simple bubbling technique. The saturated aqueous solution was treated with pyridiene and $\ce{HCl}$ solution to generate a yellow color which was measured spectrophotometrically using a filter transmitting at 430 m. u.
Sample Information:
- Source and purity not given.
- Distilled.
Measurement Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): ±3.0%.
System Components:
- Trichloroethylene, $\ce{ C2HCl3 }$; [79-01-6] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 a | $x_{1}$ | $L$ |
|---|---|---|---|
| 20 | 0.126 | 1.72 x 10-4 | 3.0 |
| 37 | 0.137 | 1.89 x 10-4 | 1.6 |
