Components:
(1) Hexachloroethane,
C2Cl6; [67-72-1]
NIST WebBook
(2) Water,
H2O; [7732-18-5]
NIST WebBook
Original Measurements
Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).
Variables:
Ambient temperature: 283 - 303 K
Prepared by:
Method/Apparatus/Procedure:
250 cm3 bottles were filled with distilled and deionized water and sealed. A measured volume of hexachloroethane was injected into the bottles through each septum using a microliter syringe. Hexachloroethane was in excess of the anticipated solubility limit. The bottles were shaken for one hour with a wrist-action shaker and allowed to equilibrate for about three weeks. Samples were then injected into a gas chromatograph equipped with a Carbopack column and a FID detector.The GC response was compared with calibration plots.
Source and Purity of Materials:
- Probably a commercial reagent, at least 99% pure, used as received.
- Distilled and deionizes.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Experimental Values:
| T (°C) | MR1 (g1/g2) | 100w1 | x1 |
|---|---|---|---|
| 10.0 | 4.1 x 10-5 | 4.1 x 10-3 | 3.12 x 10-6 |
| 20.0 | 3.7 x 10-5 | 3.7 x 10-3 | 2.82 x 10-6 |
| 30.0 | 4.1 x 10-5 | 4.1 x 10-3 | 3.12 x 10-6 |
