Compilation - Bromoethane with Water (IUPAC SDS Volume 67)
SDS Volume (3341)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 611
Original Measurements
Rex, A.; Z. Phys. Chem. 1906, 55U, 355-70.
Variables:
Room Temp: 273 - 303 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The solubility of bromoethane in water was determined using specially designed flasks with calibrated capillary cylinders. After the samples were equilibrated in a thermostatic bath at the desired temperature, the volume and the weight of the samples were determined and the solubility calculated.
Source and Purity of Materials:
- Merck, redistilled and washed before use, BP = 37.7°C.
- Distilled.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Components:
- Bromoethane, $\ce{ C2H5Br }$; [74-96-4] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | MR1 (g1/g2) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 0 | 0.01067 | 1.055 | 1.76 x 10-3 |
| 10 | 9.65 x 10-3 | 0.956 | 1.59 x 10-3 |
| 20 | 9.14 x 10-3 | 0.906 | 1.51 x 10-3 |
| 30 | 8.96 x 10-3 | 0.888 | 1.48 x 10-3 |
