SDS Volume
Volume 67. Halogenated Ethanes and Ethenes with Water, p 609
Source Publication
Svetlanov, E. B.; Velichko, S. M.; Levinskii, M. I.; Treger, Yu. A.; Flid, R. M.; Russ. J. Phys. Chem. 1971, 45, 488-90.
Conditions:
Room Temp: 303 - 333 $\pu{K}$
Compiler:
Methodology:
The dynamic method used for the solubility determination consisted of the saturation of nitrogen with 1,2-dichloroethane vapor which was then bubbled through a thermostatically controlled flask filled with a definite volume of water. After 2-3 hours the solution became saturated and samples were taken periodically [1]. The concentration of the 1,2-dichloroethane in the solution was determined by GLC. Some 3-5 measurements were taken at each temperature.
Sample Information:
- Source and purity not given.
- Source and purity not given.
- Distilled (compiler).
Measurement Errors:
Ambient temperature: ±0.05 K.
Mass concentration (m/v) (1): ±15%.
System Components:
- 1,2-Dichloroethane, $\ce{ C2H4Cl2 }$; [107-06-2] NIST WebBook
- Hydrogen chloride, $\ce{ HCl }$; [7647-01-0] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | w1 | 100w1 a | $x_{1}$ |
|---|---|---|---|
| 30 | 8.20 x 10-3 | 0.820 | 1.584 x 10-4 |
| 45 | 5.26 x 10-3 | 0.526 | 1.013 x 10-4 |
| 60 | 3.04 x 10-3 | 0.304 | 5.844 x 10-5 |
| 30 | 8.04 x 10-3 | 0.804 | 1.641 x 10-4 |
| 45 | 5.68 x 10-3 | 0.568 | 1.156 x 10-4 |
| 60 | 3.00 x 10-3 | 0.300 | 6.093 x 10-5 |
