Compilation - 1,2-Dichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3326)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 604
Original Measurements
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Variables:
Room Temp: 274 - 300 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A 5 μL 1,2-dichloroethane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,2-dichloroethane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Source and Purity of Materials:
- Source and purity not given.
- Distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±5.0%.
Components:
- 1,2-Dichloroethane, $\ce{ C2H4Cl2 }$; [107-06-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | DL |
|---|---|---|---|
| 1.0 | 0.5256 | 9.610 x 10-4 | 30.62 |
| 1.3 | 0.5363 | 9.807 x 10-4 | 30.89 |
| 11.0 | 0.6032 | 1.1035 x 10-3 | 46.56 |
| 21.0 | 0.6801 | 1.2451 x 10-3 | 68.89 |
| 22.0 | 0.6426 | 1.1761 x 10-3 | 76.59 |
| 27.2 | 0.6548 | 1.1985 x 10-3 | 95.46 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
