Compilation - Cyclohexane with Water (IUPAC SDS Volume 37)

SDS Volume (327)

Volume 37. Hydrocarbons in Water and Seawater, Part I, p 247

Original Measurements

Bröllos, K.; Peter, K.; Schneider, G. M.; Ber. Bunsenges. Phys. Chem. 1970, 74, 682-6.

Variables:

Room Temp: Pressure and temperature on one phase-two phase boundary $\pu{bar}$

Prepared by:

C.L. Young

Method/Apparatus/Procedure:

Measurements were made in a steel optical cell within an aluminum block furnace. The cell contents were stirred magnetically. Pressure was measured using a movable piston and Bourdon gauge. Temperature was measured with a steel-sheathed thermocouple. Components were charged into the cell and the transition from one phase to two phases was observed visually.

Source and Purity of Materials:
  1. Merck sample purity 99.9 mole%.
  2. Twice distilled.
Estimated Errors:

Ambient temperature: δT/K = ±0.1
Pressure: δP/P = ±0.01 (estimated by compiler)

Components:
  1. Cyclohexane, $\ce{ C6H12 }$; [110-82-7] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Values of pressure and temperature on the one phase-two phase boundary
$T$ ($\pu{K}$) $P$ ($\pu{bar}$) $x_{1}$ MR1 (g1/100 g2)
379.81.742 x 103 0.10034.1
369.01.403 x 103 0.10034.1
363.01.200 x 103 0.10034.1
360.11.000 x 103 0.10034.1
351.5798 0.10034.1
343.5595 0.10034.1
333.7395 0.10034.1
329.2328 0.10034.1
330.0293 0.10034.1
333.0271 0.10034.1
334.2245 0.10034.1
338.0217 0.10034.1
392.21.600 x 103 0.15045.2
384.01.400 x 103 0.15045.2
376.51.202 x 103 0.15045.2
369.21.000 x 103 0.15045.2
361.2800 0.15045.2
351.0600 0.15045.2
346.5500 0.15045.2
340.0394 0.15045.2
338.0347 0.15045.2
339.0299 0.15045.2
340.5250 0.15045.2
357.7222 0.15045.2
403.51.610 x 103 0.20053.9
393.91.408 x 103 0.20053.9
387.01.204 x 103 0.20053.9
378.71.002 x 103 0.20053.9
369.0800 0.20053.9
359.5600 0.20053.9
352.2500 0.20053.9
347.0416 0.20053.9
343.0328 0.20053.9
342.0298 0.20053.9
345.0246 0.20053.9
355.0223 0.20053.9
412.41.600 x 103 0.29866.5
404.71.400 x 103 0.29866.5
396.21.200 x 103 0.29866.5
387.11.004 x 103 0.29866.5
375.3800 0.29866.5
363.8600 0.29866.5
360.4550 0.29866.5
349.2398 0.29866.5
346.2339 0.29866.5
346.5237 0.29866.5
349.5224 0.29866.5
352.7214 0.29866.5
414.91.600 x 103 0.40075.7
406.51.398 x 103 0.40075.7
399.21.200 x 103 0.40075.7
390.1995 0.40075.7
378.0800 0.40075.7
364.3600 0.40075.7
355.6465 0.40075.7
347.6352 0.40075.7
345.0295 0.40075.7
342.0230 0.40075.7
335.0195 0.40075.7
421.51.718 x 103 0.50082.4
419.01.645 x 103 0.50082.4
416.51.584 x 103 0.50082.4
408.01.406 x 103 0.50082.4
399.01.195 x 103 0.50082.4
388.91.004 x 103 0.50082.4
376.0789 0.50082.4
364.0600 0.50082.4
350.0460 0.50082.4
340.1375 0.50082.4
343.0330 0.50082.4
338.5250 0.50082.4
330.0200 0.50082.4
413.01.603 x 103 0.60087.5
405.41.405 x 103 0.60087.5
395.81.200 x 103 0.60087.5
386.41.000 x 103 0.60087.5
375.3800 0.60087.5
362.0595 0.60087.5
345.7395 0.60087.5
336.2319 0.60087.5
333.4290 0.60087.5
329.4261 0.60087.5
326.5243 0.60087.5
323.1220 0.60087.5
318.5205 0.60087.5
406.71.600 x 103 0.70091.6
499.01.405 x 103 0.70091.6
389.11.200 x 103 0.70091.6
380.51.000 x 103 0.70091.6
367.2800 0.70091.6
351.1588 0.70091.6
332.5400 0.70091.6
325.0342 0.70091.6
314.0299 0.70091.6
300.5250 0.70091.6
395.41.605 x 103 0.80096.9
387.11.403 x 103 0.80096.9
377.61.200 x 103 0.80096.9
367.21.005 x 103 0.80096.9
353.9800 0.80096.9
337.5600 0.80096.9
316.5400 0.80096.9
305.0295 0.80096.9
295.1244 0.80096.9
275.2200 0.80096.9

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