Components:
(1) 1,1-Dichloroethane,
C2H4C12; [75-34-3]
NIST WebBook
(2) Water,
H2O; [7732-18-5]
NIST WebBook
Original Measurements
Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).
Variables:
Ambient temperature: 283 - 303 K
Prepared by:
Method/Apparatus/Procedure:
250 cm3 bottles were filled with distilled deionized water and sealed. Measured volumes of 1,1-dichloroethane were injected into the bottles through each bottle septum using a microliter syringe. The solute was in excess of the anticipated solubility limit. The bottles were shaken for 1 hour with a wrist-action shaker and allowed to equilibrate for about three weeks. Samples were then injected into a gas chromatograph equipped with a Carbopack column and a FID detector.The GC responses were compared with calibration plots to establish concentrations.
Source and Purity of Materials:
- Probable a commercial reagent at least 99% pure, used as received.
- Distilled and deionized.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Experimental Values:
| T (°C) | MR1 (g1/g2) | 100w1a | x1 |
|---|---|---|---|
| 10.0 | 7.435 x 10-3 | 7.435 x 10-1 | 1.3613 x 10-3 |
| 20.0 | 7.137 x 10-3 | 7.137 x 10-1 | 1.3069 x 10-3 |
| 30.0 | 6.13 x 10-3 | 6.130 x 10-1 | 1.1216 x 10-3 |
