Compilation - 1,1-Dichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3266)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 575
Original Measurements
Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).
Variables:
Room Temp: 283 - 303 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
250 mL bottles were filled with distilled deionized water and sealed. Measured volumes of 1,1-dichloroethane were injected into the bottles through each bottle septum using a microliter syringe. The solute was in excess of the anticipated solubility limit. The bottles were shaken for one hour with a wrist-action shaker and allowed to equilibrate for about three weeks. Samples were then injected into a gas chromatograph equipped with a Carbopack column and a FID detector. The GC responses were compared with calibration plots to establish concentrations.
Source and Purity of Materials:
- Probable a commercial reagent at least 99% pure, used as received.
- Distilled and deionized.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Components:
- 1,1-Dichloroethane, $\ce{ C2H4C12 }$; [75-34-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | MR1 (g1/g2) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 10 | 7.435 x 10-3 | 0.7435 | 1.3613 x 10-3 |
| 20 | 7.137 x 10-3 | 0.7137 | 1.3069 x 10-3 |
| 30 | 6.13 x 10-3 | 0.6130 | 1.1216 x 10-3 |
