Compilation - 1,1-Dichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3263)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 574
Original Measurements
Barr, R. S.; Newsham, D. M. T.; Fluid Phase Equilib. 1987, 35, 189-205.
Variables:
Room Temp: 293 - 323 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The water-rich mixture was studied using gas-liquid chromatography in which a mixture of methane and 1,1-dichloroethane vapor passed through the sampling loop. The eluted 1,1-dichloroethane was determined with a flame ionization detector. The organic-rich mixture was studied using an isopiestic method in which $\ce{CaCl2}$ solution controlled the partial pressure of water. The water concentration of the sample was determined using a Karl Fischer titration apparatus.
Source and Purity of Materials:
- Fluochem Limited. Redistilled in a glass sieve tray column.
- Double distilled tap water.
Estimated Errors:
Ambient temperature: ±0.05 K.
Mass concentration (m/v) (1): Not specified.
Components:
- 1,1-Dichloroethane, $\ce{ C2H4C12 }$; [75-34-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
Mole fraction of 1,1-dichloroethane (x1) was calculated from the activity coefficients at infinite dilution (γ∞1) using the relation x1 = 1/γ∞1.
| $T$ (°C) | $x_{1}$ | $x_{2}$ | $x_{2}$ | 100w1 | 100w2 |
|---|---|---|---|---|---|
| 20 | 9.26 x 10-4 | 5.82 x 10-3 | 5.82 x 10-3 | 0.507 | 1.06 x 10-3 |
| 35 | 8.93 x 10-4 | - | - | 0.489 | - |
| 50 | 9.26 x 10-4 | 0.0105 | 0.0105 | 0.507 | 1.93 x 10-3 |
