Compilation - Water with 1,1-Dichloroethane (IUPAC SDS Volume 67)
SDS Volume (3253)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 569
Original Measurements
Staverman, A. J.; Recl. Trav. Chim. Pays-Bas 1941, 60, 836-41.
Variables:
Room Temp: 273 - 303 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Water was shaken with 1,1-dichloroethane for about 12 hours in a paraffin liquid bath thermostat. The water content of the organic phase was determined by the Karl Fischer titration method. All measurements were carried out in duplicate. The result is an average of two measurements. A full description of the method used is given in a thesis [1].
Source and Purity of Materials:
- Distilled.
- Source and purity not given.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
References
1 Staverman, A. J.; Ph.D. Dissertation, University of Leiden, Leiden, Belgium, 1938.
Components:
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
- 1,1-Dichloroethane, $\ce{ C2H4C12 }$; [75-34-3] NIST WebBook
Experimental Data
| $T$ (°C) | w1 | $x_{1}$ | $mol_{1}/\pu{100 g}$ (mol/g) |
|---|---|---|---|
| 0 | 4.60 x 10-4 | 2.54 x 10-3 | 2.55 x 10-5 |
| 25 | 9.66 x 10-4 | 5.31 x 10-3 | 5.36 x 10-5 |
| 30 | 1.145 x 10-3 | 6.30 x 10-3 | 6.36 x 10-5 |
