Compilation - 1,1-Dichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3250)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 568
Original Measurements
Gross, P. M.; J. Am. Chem. Soc. 1929, 51, 2362-6.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A weighted amount of 1,1-dichloroethane was mixed with 1000 g water in a bottle and immersed in a waterbath thermostat. The bottle was placed on a shaker and shaken until no more droplets of the liquid remained undissolved. The concentration of 1,1-dichloroethane in water was determined using a Zeiss water interferometer. One or more samples were syphoned out for the determination of the solubility. The German translation of the article is also published [1].
Source and Purity of Materials:
- Commercial reagent, fractionally distilled before use.
- Distilled.
Estimated Errors:
Ambient temperature: ±0.01 K.
Mass concentration (m/v) (1): ±2.0%.
References
Components:
- 1,1-Dichloroethane, $\ce{ C2H4C12 }$; [75-34-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | MR1 (g1/g2) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 25 | 5.06 x 10-3 | 0.503 | 9.19 x 10-4 |
