Compilation - Water-d2 with 1,2-Dibromoethane (IUPAC SDS Volume 67)
SDS Volume (3246)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 565
Original Measurements
Hutchinson, C. A.; Lyon, A. M.; Columbia University Report A-745, July 1, 1943.
Variables:
Room Temp: 298 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A mixture of 1 to 15 volume ratio of heavy water and 1,2-dibromoethane was introduced into an equilibration flask and then lowered into a waterbath thermostat. The assembly was shaken mechanically for about 90 minutes at constant temperature. The amount of heavy water in the organic phase was determined by a modified Karl Fischer titration method. The determination was done in triplicate. This procedure description was taken from a secondary source [1]. The original university report is no longer available.
Source and Purity of Materials:
- Source and purity not given.
- Probably a commercial reagent, further purified and dryed before use.
Estimated Errors:
Ambient temperature: ±0.05 K.
Mass concentration (m/v) (1): ±1.0 × 10-5. av. dev.
References
1 Eidinoff, M. L.; Joris, G. G.; Taylor, H. S.; Urey, H. C.; eds., Production of Heavy Water (McGraw_Hill, New York, 1955), p. 129.
Components:
- Water-d2, $\ce{ D2O }$; [7789-20-0] NIST WebBook
- 1,2-Dibromoethane, $\ce{ C2H4Br2 }$; [106-93-4] NIST WebBook
Experimental Data
| $T$ (°C) | $mol_{1}/\pu{100 g}$ (mol/g) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 25 | 2.79 x 10-3 | 0.0559 | 5.22 x 10-3 |
