SDS Volume
Volume 67. Halogenated Ethanes and Ethenes with Water, p 546
Source Publication
Leighton, D. T.; Calo, J. M.; J. Chem. Eng. Data 1981, 26, 382-5.
Conditions:
Room Temp: 276 - 299 $\pu{K}$
Compiler:
Methodology:
A 5 μL 1,1,2-trichloroethane sample was injected into a 2.3 L equilibration cell containing distilled water. After the cell was shaken vigorously for about 5 minutes, the homogeneity of the liquid sample was maintained with a magnetic stirrer. Compressed air was passed through the cell and the gas flow was measured with a soap film flowmeter. The 1,1,2-trichloroethane content was extracted and analyzed using a dual flame ionization detector gas chromatograph.
Sample Information:
- Source and purity not given.
- Distilled.
Measurement Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±10%.
System Components:
- 1,1,2-Trichloroethane, $\ce{ C2H3Cl3 }$; [79-00-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 a | $x_{1}$ a | DL |
|---|---|---|---|
| 2.5 | 0.3705 | 5.0191 x 10-4 | 16.67 |
| 7.0 | 0.3891 | 5.2719 x 10-4 | 20.96 |
| 12.9 | 0.4323 | 5.8595 x 10-4 | 26.91 |
| 18.0 | 0.4523 | 6.1327 x 10-4 | 34.14 |
| 19.5 | 0.4985 | 6.7619 x 10-4 | 33.64 |
| 24.3 | 0.4922 | 6.6761 x 10-4 | 44.61 |
| 26.1 | 0.4902 | 6.6486 x 10-4 | 48.47 |
(a) Gas-liquid system analysis parameter, from calibration measurements.
