Compilation - 1,1,2-Trichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3205)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 546
Original Measurements
Newsham, D. M. T.; Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).
Variables:
Room Temp:
321
$\pu{K}$
Pressure:
mmHg=6 - 48
mm Hg
Prepared by:
Method/Apparatus/Procedure:
Samples were equilibrated for at least ten days in a waterbath thermostat. The concentration of 1,1,2-trichloroethane in water was determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an automatic digital integrator. A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.
Source and Purity of Materials:
- Source not given, contained less than 0.1% dissolved material.
- Distilled (compiler).
Estimated Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±1%.
Components:
- 1,1,2-Trichloroethane, $\ce{ C2H3Cl3 }$; [79-00-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $P$ (mm Hg) | $x_{1}$ | 100w1 |
|---|---|---|---|
| 48.2 | 6.03 | 3.9 x 10-5 | 0.0288 |
| 48.2 | 12.2 | 8.6 x 10-5 | 0.0636 |
| 48.2 | 14.5 | 1.10 x 10-4 | 0.0814 |
| 48.2 | 18.0 | 1.24 x 10-4 | 0.0918 |
| 48.2 | 31.4 | 2.77 x 10-4 | 0.205 |
| 48.2 | 47.6 | 4.49 x 10-4 | 0.331 |
