SDS Volume
Volume 67. Halogenated Ethanes and Ethenes with Water, p 545
Source Publication
Newsham, D. M. T.; Measurement and Correlation of Thermodynamic Data for Chlorinated Hydrocarbons, UMIST, Manchester (January. 1981).
Conditions:
Room Temp: 286 - 323 $\pu{K}$
Compiler:
Methodology:
Samples were equilibrated for at least ten days in waterbath thermostat. The concentration of 1,1,2-trichloroethane in water was determined using a Perkin-Elmer model 900 gas chromatograph equipped with a flame ionization detector and an automatic digital integrator. A helium carrier gas and a Poropack QS column were used for the chromatographic analyses.
Sample Information:
- Source not given, contained less than 0.1% dissolved material.
- Distilled (compiler).
Measurement Errors:
Ambient temperature: ±0.1 K.
Mass concentration (m/v) (1): ±1%.
System Components:
- 1,1,2-Trichloroethane, $\ce{ C2H3Cl3 }$; [79-00-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | 100w1 a | $mol_{1}/\pu{100 g}$ (mol/g) a |
|---|---|---|---|
| 12.5 | 5.86 x 10-4 | 4.32 x 10-3 | 3.24 x 10-5 |
| 14.0 | 5.73 x 10-4 | 4.23 x 10-3 | 3.17 x 10-5 |
| 21.0 | 5.77 x 10-4 | 4.26 x 10-3 | 3.19 x 10-5 |
| 21.6 | 5.87 x 10-4 | 4.33 x 10-3 | 3.25 x 10-5 |
| 25.0 | 5.83 x 10-4 | 4.30 x 10-3 | 3.22 x 10-5 |
| 30.0 | 6.19 x 10-4 | 4.56 x 10-3 | 3.42 x 10-5 |
| 35.0 | 6.00 x 10-4 | 4.42 x 10-3 | 3.31 x 10-5 |
| 40.0 | 6.46 x 10-4 | 4.76 x 10-3 | 3.57 x 10-5 |
| 50 | 7.58 x 10-4 | 5.58 x 10-3 | 4.18 x 10-5 |
