Compilation - 1,1,1-Trichloroethane with Water (IUPAC SDS Volume 67)
SDS Volume (3172)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 530
Original Measurements
Schwarz, F. P.; Miller, J.; Anal. Chem. 1980, 52(13), 2162-4.
Variables:
Room Temp: 283 - 303 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The aqueous solubility was determined by elution chromatography. The solute columns (3 mm o.d., 1.8 mm i.d.) were positioned vertically in a waterbath thermostat. The measurement time interval ranged from one day to two weeks. The average deviations were calculated from several measurements on different samples. The elution chromatography method has been described elsewhere [1].
Source and Purity of Materials:
- Source not given. Commercial reagent, 98 wt.% pure, used as received.
- Distilled.
Estimated Errors:
Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±4%.
References
Components:
- 1,1,1-Trichloroethane, $\ce{ C2H3Cl3 }$; [71-55-6] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | $mol_{1}/\pu{100 g}$ (mol/g) |
|---|---|---|---|
| 10.0 | 0.180 | 2.43 x 10-4 | 1.35 x 10-5 |
| 20.0 | 0.185 | 2.50 x 10-4 | 1.39 x 10-5 |
| 30.0 | 0.159 | 2.15 x 10-4 | 1.19 x 10-5 |
