Compilation - trans-1,2-Dichloroethene (trans-1,2-dichloro-ethylene) with Water (IUPAC SDS Volume 67)
SDS Volume (3103)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 496
Original Measurements
Gossett, J. M.; Environ. Sci. Technol. 1987, 21, 202-8.
Variables:
Room Temp: 283 - 308 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A modification of the EPICS procedure was used for measuring Henry's law constants. A precise quantity of trans-1,2-dichloroethene was injected into srum bottles which contained distilled water. The bottles were incubated for 18-24 hours at four desired temperatures in a reciprocating shaker bath. The headspace concentrations of the EPICS bottles were measured by a gas chromatograph which was equipped with a flame ionization detector. The mean of the coefficient of variation values was about 4.3%.
Source and Purity of Materials:
- Commercial grade, source not given.
- Distilled (compiler).
Estimated Errors:
Ambient temperature: ±0.1 K (compiler).
Mass concentration (m/v) (1): (2) Distilled
Components:
- trans-1,2-Dichloroethene, $\ce{ C2H2Cl2 }$; [156-60-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | $k_{\rm{D}}$ (m3 atm mol-1) |
|---|---|---|---|
| 10.0 | 0.5354 | 9.993 x 10-4 | 4.20 x 10-3 |
| 17.5 | 0.4738 | 8.839 x 10-4 | 6.60 x 10-3 |
| 24.8 | 0.4544 | 8.475 x 10-4 | 9.38 x 10-3 |
| 34.6 | 0.4539 | 8.466 x 10-4 | 0.0138 |
(a) CV = coefficient of variation ( = 100 S.D./mean).
