SDS Volume (3091)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 489
Original Measurements
Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).
Variables:
Room Temp: 283 - 303 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
250 mL bottles were filled with distilled and deionized water and sealed. A measured volume of 1,1-dichloroethene was injected into the bottles through each septum using a microliter syringe. The 1,1-dichloroethene was in excess of the anticipated solubility limit. The bottles were shaken for one hour with a wrist-action shaker and allowed to equilibrate for about three weeks. Samples were then injected into a gas chromatograph equipped with a Carbopac Column and a FID detector. The GC response was compared with calibration plots.
Source and Purity of Materials:
- Probably a commercial reagent, at least 99% pure, used as received.
- Distilled and deionized.
Estimated Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
Components:
- 1,1-Dichloroethene, $\ce{ C2H2Cl2 }$; [75-35-4] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | MR1 (g1/g2) | 100w1 | $x_{1}$ |
|---|---|---|---|
| 10 | 6.3 x 10-4 | 0.0630 | 1.171 x 10-4 |
| 20 | 7.5 x 10-4 | 0.0750 | 1.395 x 10-4 |
| 30 | 6.56 x 10-4 | 0.0656 | 1.220 x 10-4 |
