SDS Volume
Volume 67. Halogenated Ethanes and Ethenes with Water, p 469
Source Publication
Howe, G. B.; Mullins, M. E.; Rogers, T. N.; AFESC Tyndall Air Force Base, Report ESL-TR-86-66, Vol. 1, Florida, Sept. 1987, 86 pp. (AD-A188 571).
Conditions:
Room Temp: 283 - 303 $\pu{K}$
Compiler:
Methodology:
250 mL bottles were filled with distilled and deionized water and sealed. A measured volume of trichloroethene was injected into the bottles through each septum using a microliter syringe. Trichloroethene was in excess of the anticipated solubility limit. The bottles were shaken for one hour with a wrist-action shaker and allowed to equilibrate for about three weeks. Samples were then injected into a gas chromatograph equipped with a Carbopac Column and a FID detector. The GC response wascompared with calibration plots.
Sample Information:
- Probably a commercial grade at least 99% pure, used as received.
- Distilled and deionized.
Measurement Errors:
Ambient temperature: ±0.5 K (compiler).
Mass concentration (m/v) (1): Not specified.
System Components:
- Trichloroethylene, $\ce{ C2HCl3 }$; [79-01-6] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | MR1 (g1/g2) | 100w1 a | $x_{1}$ |
|---|---|---|---|
| 10 | 1.499 x 10-3 | 0.1499 | 2.0574 x 10-4 |
| 20 | 1.194 x 10-3 | 0.1194 | 1.6388 x 10-4 |
| 30 | 1.401 x 10-3 | 0.1401 | 1.9233 x 10-4 |
