SDS Volume (3039)
Volume 67. Halogenated Ethanes and Ethenes with Water, p 465
Original Measurements
Orlandini, M.; Fermeglia, M.; Kikic, I.; Alessi, P.; Chem. Eng. J. 1983, 26, 245-50.
Variables:
Room Temp: 293 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
A mixture of trichloroethene and water was agitated overnight and left at equilibrium for 24 hours. Three samples were withdrawn for each phase with a syringe and analyzed by gas chromatography. The gas chromatograph (C. Erba ATc/t) was equipped with a Shimadzu Chromatopac E-1A integrator. A stainless column packed with 100-120 mesh Chromosorb W DMCD coated with heptadecane nitrile was used for analysis.
Source and Purity of Materials:
- Fluka reagent, purified by distillation before use.
- Distilled (compiler).
Estimated Errors:
Ambient temperature: +/-0.1 K
Mass concentration (m/v) (1): Not specified.
Components:
- Trichloroethylene, $\ce{ C2HCl3 }$; [79-01-6] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | $x_{1}$ | $x_{2}$ | 100w1 | 100w2 |
|---|---|---|---|---|
| 20 | 5.5 x 10-4 | 9.9 x 10-3 | 0.400 | 0.137 |
