Compilation - Cyclohexene with Water (IUPAC SDS Volume 37)
SDS Volume (293)
Volume 37. Hydrocarbons in Water and Seawater, Part I, p 206
Original Measurements
Pierotti, R. A.; Liabastre, A. A.; "Structure and properties of water solutions. " U. S. Nat. Tech. Inform. Serv.; PB Rep.; 1972, No. 21163, 113 p.
Variables:
Room Temp: 278.26 - 318.36 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
10 mL of (2) were placed along with 4-10 drops (1) in 10 mL serum bottles, which were then tightly capped, and placed in the rotating basket and rotated for 24 hours. The bottles were then hand shaken to remove (1) droplets from the stoppers and then replaced in the bath with tops down for an additional 24 hours. The solute concentrations were determined by use of a flame-ionization gas chromatograph. Many details about equipment, operating conditions and calculation are given in the paper.
Source and Purity of Materials:
- Eastman Organic Chemicals, No. 1043; washed with water to remove stabilizing agent.
- laboratory distilled water
Estimated Errors:
Mass concentration (m/v) (1): standard deviation from at least 15 measurements are given above.
Components:
- Cyclohexene, $\ce{ C6H10 }$; [110-83-8] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
The solubility of cyclohexene in water at 20°C was reported to be x1 = 5 × 10-5.
The corresponding mass percent calculated by the compiler is 0.023 g(1)/100 g sln.
The solubility of water in cyclohexene at 20°C was reported to be x2 = 0.0019.
The corresponding mass percent calculated by the compiler is 0.042 g(2)/100 g sln.
Solubility of cyclohexene in water
| $T$ ($\pu{K}$) | $x_{1}$ | MR2 (g1/100 g2) |
|---|---|---|
| 278.26 | 6.141 x 10-5 | 0.02800 |
| 288.36 | 6.546 x 10-5 | 0.02985 |
| 298.26 | 6.557 x 10-5 | 0.02990 |
| 308.36 | 6.634 x 10-5 | 0.03025 |
| 318.36 | 6.809 x 10-5 | 0.03105 |
