NIST-IUPAC Solubility Data Series

Carbon dioxide with Ammonium chloride, Ammonium sulfate and Water (IUPAC SDS Volume 62)

SDS Volume

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Source Publication

Yasunishi, A.; Tsuji, M.; Sada, E.; Adv. Chem. Ser. 1979, 177, 189-203.

Conditions:

Room Temp: 298.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): (C₂ + C₃)/mol dm^-3 = 0 - 2.873 mol/L

Compiler:

C.L. Young

Methodology:

Volumetric apparatus with multibulb buret and magnetic stirrer. Amount of solution and gas absorbed determined volumetrically. Partial pressure determined from total pressure and vapor pressure of solution. The vapor pressure of the mixed salt solution estimated by the method of Robinson and Bower [1] from corresponding data for each component salt solution. Apparatus similar to that described in [2].

Sample Information:

Extra pure grade, purity 99.96 mole%.
(2,3) Reagent grade.
Deionized.

Measurement Errors:

Ambient temperature: δT/K = ±0.05
Mass concentration (m/v) (1): δL = ±1%

Methodology Citations

¹ Robinson, R. A.; Bower, V. E.; J. Res. Nat. Bur. Stand. 1965, 69A, 365.
² Tokunaga, J.; J. Chem. Eng. Data 1975, 20, 41.

System Components:

Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
Ammonium chloride, $\ce{ NH4Cl }$; [12125-02-9] NIST WebBook
Ammonium sulfate, $\ce{ (NH4)2SO4 }$; [7783-20-2] NIST WebBook
Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook

Experimental Data

$T$ ($\pu{K}$)	$x_{2}$	$P_{1}$ ($\pu{kPa}$)	$L$	$C_{2+3}$ (mol/dm³)
298.15	0^b	101.325	0.8264^a	0
298.15	0^b	101.325	0.7378^a	0.253
298.15	0^b	101.325	0.6572^a	0.519
298.15	0^b	101.325	0.5794^a	0.845
298.15	0^b	101.325	0.4978^a	1.235
298.15	0^b	101.325	0.3952^a	1.836
298.15	0^b	101.325	0.3161^a	2.486
298.15	0^b	101.325	0.2802^a	2.873
298.15	0.25^b	101.325	0.7505^a	0.282
298.15	0.25^b	101.325	0.6785^a	0.573
298.15	0.25^b	101.325	0.5961^a	0.998
298.15	0.25^b	101.325	0.5322^a	1.396
298.15	0.25^b	101.325	0.4580^a	1.946
298.15	0.25^b	101.325	0.4015^a	2.433
298.15	0.50^b	101.325	0.3687^a	2.806
298.15	0.50^b	101.325	0.7568^a	0.333
298.15	0.50^b	101.325	0.6997^a	0.658
298.15	0.50^b	101.325	0.6460^a	1.021
298.15	0.50^b	101.325	0.5959^a	1.330
298.15	0.50^b	101.325	0.5223^a	2.014
298.15	0.75^b	101.325	0.4578^a	2.673
298.15	0.75^b	101.325	0.7905^a	0.254
298.15	0.75^b	101.325	0.7451^a	0.601
298.15	0.75^b	101.325	0.6978^a	1.018
298.15	0.75^b	101.325	0.6594^a	1.414
298.15	0.75^b	101.325	0.6133^a	1.985
298.15	0.75^b	101.325	0.5800^a	2.400
298.15	1.00^b	101.325	0.5524^a	2.861
298.15	1.00^b	101.325	0.7658^a	0.375
298.15	1.00^b	101.325	0.7704^a	0.811
298.15	1.00^b	101.325	0.7460^a	1.147
298.15	1.00^b	101.325	0.7328^a	1.508
298.15	1.00^b	101.325	0.7102^a	1.973
298.15	1.00^b	101.325	0.6915^a	2.338
298.15	1.00^b	101.325	0.6721^a	2.816

(a) L = Ostwald coefficient [cm³ cm^-3]

(b) In NH₄Cl + (NH₄)₂SO₄ mixed salt.

IUPAC-NIST Solubility Data Series, SRD 106