SDS Volume (2836)

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Original Measurements

Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.

Variables:

Room Temp: 288.15 - 333.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol dm-3 = 0 - 2 g/L

Prepared by:

D.M. Mason

Method/Apparatus/Procedure:

The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].

Source and Purity of Materials:
  1. VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
  2. DDR pro analysis grade by DDR Standard TGL 5021.
  3. Double distilled.
Estimated Errors:

Ambient temperature: Not given.

References

1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.

Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Ammonium sulfate, $\ce{ (NH4)2SO4 }$; [7783-20-2] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $C_{2}$ (mol/dm3) α ($\pu{cm3(g) cm-3(l) atm-1}$) $S$
288.15150 0.990-
288.15150.25 0.9150.928
288.15150.5 0.8250.850
288.15151 0.6480.688
288.15152 0.4770.548
293.15200 0.860-
293.15200.25 0.8110.823
293.15200.5 0.7380.761
293.15201 0.5740.611
293.15202 0.4240.4875
298.15250 0.7580.5173
298.15250.25 0.7180.7295
298.15250.5 0.6690.690
298.15251 0.5150.549
298.15252 0.3740.431
303.15300 0.671-
303.15300.25 0.6340.645
303.15300.5 0.5790.598
303.15301 0.4650.4965
303.15302 0.3310.383
308.15350 0.605-
308.15350.25 0.5640.574
308.15350.5 0.5160.533
308.15351 0.4090.4375
308.15352 0.2960.3425
313.15400 0.546-
313.15400.25 0.5020.512
313.15400.5 0.4610.477
313.15401 0.3620.388
313.15402 0.2620.3035
318.15450 0.482-
318.15450.25 0.4480.4575
318.15450.5 0.4090.4245
318.15451 0.3270.351
318.15452 0.2410.2793
323.15500 0.436-
323.15500.25 0.3960.405
323.15500.5 0.3680.383
323.15501 0.2990.3215
323.15502 0.2150.250
328.15550 0.392-
328.15550.25 0.3560.3645
328.15550.5 0.3340.348
328.15551 0.2720.2927
328.15552 0.1890.220
333.15600 0.372-
333.15600.25 0.3230.331
333.15600.5 0.3080.321
333.15601 0.2520.273
333.15602 0.1750.2043

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

(b) S = Kuenen coefficient [cm3 (STP) g-1 (H2O) atm-1].

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