SDS Volume
Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None
Source Publication
Onda, K.; Sada, E.; Kobayashi, T.; Kito, S.; Ito, K.; J. Chem. Eng. Jpn. 1970, 3, 18-24.
Conditions:
Room Temp:
298.15
$\pu{K}$
Pressure:
101.325
$\pu{kPa}$
Amount concentration (2):
C2/mol dm-3 = 1.482
g/L
Compiler:
Methodology:
Solution was made up by weight. Concentration of solution was verified by measuring the density. (Density was not reported in the paper.) A measured volume of gas was brought into contact with a measured quantity of gas-free solvent. Equilibrium was established by agitation using a magnetic stirrer. The volume of remaining gas was measured. The amount of gas absorbed was estimated from change in volume of gas. Details in original paper.
Sample Information:
- From commercial cylinder. Purity 99.8%.
- Analytical grade.
- Distilled and degassed.
Measurement Errors:
Ambient temperature: δT/K = ±0.2
Mass concentration (m/v) (1): δα = ±2%
System Components:
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Nitric acid, $\ce{ HNO3 }$; [7697-37-2] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $C_{2}$ (mol/dm3) | $L$ | α ($\pu{cm3(g) cm-3(l) atm-1}$) |
|---|---|---|---|
| 298.15 | 0 | 0.8290b,c | 0.7595a |
| 298.15 | 1.482 | 0.8634b,c | 0.7910a |
(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].
(b) L = Ostwald coefficient [cm3 cm-3]
(c) Calculated by the compiler. P = 1 atm = 101.325 kPa = 1.01325 bar
