Components:

(1) Benzene, C6H6; [71-43-2] NIST WebBook
(2) Sodium chloride, NaCl; [7647-14-5] NIST WebBook
(3) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Price, L. C.; Am. Assoc. Petrol. Geol. Bull. 1976, 60, 213-44.

Variables:

Ambient temperature: One temperature: 25 °C
Salinity: 1 - 360 g(2)/kg sln

Prepared by:

M. Kleinschmidt, W.Y. Shiu

Method/Apparatus/Procedure:

Details given in source. (1) was equilibrated with NaCl solution for one month. A aliquot was analyzed for one month. An aliquot was analysed directly by gas chromatography.

Source and Purity of Materials:
  1. Commercial, 99+% pure
Estimated Errors:

Ambient temperature: ±1 K
Mass concentration (m/v) (1): ±10 relative%

References

1 Lyman, J.; Fleming, R. H.; J. Mar. Res. 1940, 3, 135.

Experimental Values:
Solubility of Benzene in Aqueous NaCl
T (°C) MR1 (g1/100 g2) MR2 (g/kg) x1
25.0 1.718 x 10-1 1.002 3.96 x 10-4
25.0 1.628 x 10-1 10.0 3.78 x 10-4
25.0 1.391 x 10-1 34.472 3.28 x 10-4
25.0 1.194 x 10-1 50.03 2.85 x 10-4
25.0 5.93 x 10-2 125.1 1.48 x 10-4
25.0 3.88 x 10-2 199.9 1.01 x 10-4
25.0 2.14 x 10-2 279.8 5.81 x 10-5
25.0 1.34 x 10-2 358.7 3.78 x 10-5

(a) Artificial seawater, composition not specified but probably similar to ref 1.

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