Compilation - Carbon dioxide with Water (IUPAC SDS Volume 62)
SDS Volume (2766)
Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None
Original Measurements
Van Slyke, D. D.; J. Biol. Chem. 1939, 130, 545-54.
Variables:
Room Temp:
295.95 - 298.65
$\pu{K}$
Pressure:
101.325
$\pu{kPa}$
Prepared by:
Method/Apparatus/Procedure:
Measurements were made in a Van Slyke/Neill apparatus [1,2]. In this kind of apparatus the equilibration and analysis were done in the same chamber. Shaking was done during saturation and degassing. Once equilibration was achieved the undissolved gas was removed and the solution analyzed for absorbed gases manometrically in a known volume.
Source and Purity of Materials:
- 99.9%.
- Not specified. Degassed.
Estimated Errors:
Ambient temperature: Not stated.
References
1
Van Slyke, D. D.; Neill, J. M.; J. Biol. Chem. 1924. 61, 523-35.
2
Van Slyke, D. D.; J. Biol. Chem. 1927, 73, 121-24.
Components:
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $T$ (°C) | $x_{1}$ | $P$ ($\pu{atm}$) | α ($\pu{cm3(g) cm-3(l) atm-1}$) | $P_{\rm{c}}$ ($\pu{bar}$) |
|---|---|---|---|---|---|
| 295.95 | 22.8 | 6.534 x 10-4 | 1.00 | 0.806 | 1.041 |
| 295.95 | 22.8 | 6.542 x 10-4 | 1.00 | 0.807 | 1.041 |
| 297.85 | 24.7 | 6.197 x 10-4 | 1.00 | 0.764 | 1.044 |
| 297.95 | 24.8 | 6.148 x 10-4 | 1.00 | 0.758 | 1.045 |
| 298.55 | 25.4 | 6.101 x 10-4 | 1.00 | 0.752 | 1.046 |
| 298.65 | 25.5 | 6.109 x 10-4 | 1.00 | 0.753 | 1.046 |
(a) Calculated by the compiler.
(b) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].
(c) Assuming that Vm,1 = 22.2605 dm3 mol-1 at STP.
