SDS Volume
Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None
Source Publication
Geffcken, G.; Z. Phys. Chem. 1904, 49U, 257-302.
Conditions:
Room Temp:
288.15 - 298.15
$\pu{K}$
Amount concentration (2):
C2/mol dm-3 = 0 - 0.554
g/L
Compiler:
Methodology:
Volumetric method using simple absorption pipet and buret. Diagram and detailed description given in original paper.
Sample Information:
- Obtained by the sublimation of solid carbon dioxide. Dried.
- Not specified.
- Degassed.
Measurement Errors:
Ambient temperature: δT/K = ±0.1 (estimated by the compiler)
Mass concentration (m/v) (1): δL = ±1%(estimated by the compiler)
System Components:
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Cesium chloride, $\ce{ CsCl }$; [7647-17-8] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $C_{2}$ (mol/dm3) | $L$ |
|---|---|---|
| 288.15 | 0 | 1.070a |
| 288.15 | 0.552 | 1.001a |
| 288.15 | 0.554 | 0.9995a |
| 298.15 | 0 | 0.8255a |
| 298.15 | 0.552 | 0.7771a |
| 298.15 | 0.554 | 0.7769a |
(a) L = Ostwald coefficient [cm3 cm-3]
