SDS Volume

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Source Publication

Geffcken, G.; Z. Phys. Chem. 1904, 49U, 257-302.

Conditions:

Room Temp: 288.15 - 298.15 $\pu{K}$
Amount concentration (2): C2/mol dm-3 = 0 - 1.058 g/L

Compiler:

C.L. Young

Methodology:

Volumetric method using simple absorption pipet and buret. Diagram and detailed description given in original paper.

Sample Information:
  1. Obtained by the sublimation of solid carbon dioxide. Dried.
  2. Not specified.
  3. Degassed.
Measurement Errors:

Ambient temperature: δT/K = ±0.1 (estimated by the compiler)
Mass concentration (m/v) (1): δL = ±1% (estimated by compiler)

System Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Potassium chloride, $\ce{ KCl }$; [7447-40-7] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $C_{2}$ (mol/dm3) $L$
288.150 1.070a
288.150.423 0.9892a
288.150.432 0.9865a
288.151.045 0.8875a
288.151.058 0.8910a
298.150 0.8255a
298.150.423 0.7695a
298.150.432 0.7667a
298.151.045 0.6920a
298.151.058 0.6961a

(a) L = Ostwald coefficient (cm3 cm-3)

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