SDS Volume (2699)

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Original Measurements

Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.

Variables:

Room Temp: 288.15 - 333.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol dm-3 = 0 - 4 g/L

Prepared by:

D.M. Mason

Method/Apparatus/Procedure:

The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].

Source and Purity of Materials:
  1. VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
  2. DDR pro analysis grade by DDR Standard TGL 5021.
  3. Double distilled.
Estimated Errors:

Ambient temperature: Not given.

References

1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.

Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Sodium formate, $\ce{ NaCHO2 }$; [141-53-7] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $C_{2}$ (mol/dm3) α ($\pu{cm3(g) cm-3(l) atm-1}$) $S$
288.15150 0.990-
288.15150.1 1.0101.0145
288.15150.2 1.0281.034
288.15150.5 0.9650.978
288.15151 0.9450.970
288.15152 0.9330.9875
288.15154 1.0471.184
293.15200 0.860-
293.15200.1 0.8850.890
293.15200.2 0.9050.911
293.15200.5 0.8360.849
293.15201 0.8420.866
293.15202 0.8290.879
293.15204 0.9551.082
298.15250 0.758-
298.15250.1 0.7780.783
298.15250.2 0.7910.7975
298.15250.5 0.7410.754
298.15251 0.7470.7695
298.15252 0.7410.7875
298.15254 0.8700.988
303.15300 0.671-
303.15300.1 0.6870.692
303.15300.2 0.7170.7235
303.15300.5 0.6620.674
303.15301 0.6750.696
303.15302 0.6670.709
303.15304 0.8060.918
308.15350 0.605-
308.15350.1 0.6160.621
308.15350.2 0.6460.6525
308.15350.5 0.5940.605
308.15351 0.6110.631
308.15352 0.6110.651
308.15354 0.7290.832
313.15400 0.546-
313.15400.1 0.5600.565
313.15400.2 0.5830.583
313.15400.5 0.5310.541
313.15401 0.5530.5715
313.15402 0.5420.578
313.15404 0.6590.754
318.15450 0.482-
318.15450.1 0.5050.510
318.15450.2 0.5280.534
318.15450.5 0.4680.478
318.15451 0.5060.523
318.15452 0.5000.5355
318.15454 0.6020.691
323.15500 0.436-
323.15500.1 0.4520.457
323.15500.2 0.4800.487
323.15500.5 0.4470.456
323.15501 0.4790.496
323.15502 0.4800.515
323.15504 0.5820.670
328.15550 0.392-
328.15550.1 0.4090.414
328.15550.2 0.4340.440
328.15551 0.4620.480
328.15552 0.4560.490
328.15554 0.5670.654
333.15600 0.372-
333.15600.1 0.3730.378
333.15600.2 0.3960.402
333.15601 0.4330.451
333.15602 0.4500.484
333.15604 0.5480.635

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

(b) S = Kuenen coefficient [cm3 (STP) g-1 (H2O) atm-1].

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