SDS Volume (2644)

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Original Measurements

Onda, K.; Sada, E.; Kobayashi, T.; Kito, S.; Ito, K.; J. Chem. Eng. Jpn. 1970, 3, 18-24.

Variables:

Room Temp: 298.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol L-1 = 0 - 3.006 g/L

Prepared by:

C.L. Young

Method/Apparatus/Procedure:

Solutions made up by weight and density measured but not reported in paper. Equilibrium established between a measured volume of gas and a measured amount of gas-free liquid in a cell fitted with a magnetic stirrer. Amount of gas absorbed estimated from change in volume of gas. Details in source.

Source and Purity of Materials:
  1. Commercial sample, minimum purity 99.8 mole%
  2. Analytical grade.
  3. Distilled and degassed.
Estimated Errors:

Ambient temperature: δT/K = ±0.2 (estimated by the compiler)
Mass concentration (m/v) (1): δα = ±2% (estimated by the compiler)

Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Sodium chloride, $\ce{ NaCl }$; [7647-14-5] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data

P = 1 atm= 101.325 kPa = 1.01325 bar

$T$ ($\pu{K}$) $C_{2}$ (mol/L) α ($\pu{cm3(g) cm-3(l) atm-1}$)
298.150 0.7595
298.150.500 0.6644
298.150.603 0.6489
298.150.999 0.5972
298.151.000 0.5941
298.151.153 0.5686
298.152.000 0.4712
298.153.001 0.3776
298.153.006 0.3729

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

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