SDS Volume (2643)

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Original Measurements

Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.

Variables:

Room Temp: 288.15 - 333.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol dm-3 = 0 - 4.3 g/L

Prepared by:

D.M. Mason

Method/Apparatus/Procedure:

The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].

Source and Purity of Materials:
  1. VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
  2. DDR pro analysis grade by DDR Standard TGL 5021.
  3. Double distilled.
Estimated Errors:

Ambient temperature: Not given.

References

1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.

Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Sodium chloride, $\ce{ NaCl }$; [7647-14-5] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) α ($\pu{cm3(g) cm-3(l) atm-1}$) $S$
288.1515 0.990-
288.1515 0.8070.815
288.1515 0.7590.774
288.1515 0.6070.633
288.1515 0.4070.447
293.1520 0.860-
293.1520 0.7280.735
293.1520 0.6890.704
293.1520 0.5600.585
293.1520 0.3400.3743
298.1525 0.758-
298.1525 0.6580.666
298.1525 0.6050.619
298.1525 0.4850.5075
298.1525 0.3100.3423
303.1530 0.671-
303.1530 0.5750.582
303.1530 0.5320.545
303.1530 0.4410.463
303.1530 0.2820.312
308.1535 0.605-
308.1535 0.5150.522
308.1535 0.4770.4885
308.1535 0.4010.421
308.1535 0.2510.278
313.1540 0.546-
313.1540 0.4430.450
313.1540 0.4160.424
313.1540 0.3580.377
313.1540 0.2260.2507
318.1545 0.482-
318.1545 0.3820.388
318.1545 0.3740.385
318.1545 0.3070.324
318.1545 0.2070.2303
323.1550 0.436-
323.1550 0.3450.351
323.1550 0.3360.346
323.1550 0.2760.2915
323.1550 0.1900.2116
328.1555 0.392-
328.1555 0.2400.254
328.1555 0.1710.1911
333.1560 0.372-
333.1560 0.2790.284
333.1560 0.2660.275
333.1560 0.22250.2357
333.1560 0.1530.1714

(b) S1 = Kuenen coefficient [cm3 (STP) g-1(H2O) atm-1].

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

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