SDS Volume

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Source Publication

Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.

Conditions:

Room Temp: 288.15 - 333.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol dm-3 = 0 - 5 g/L

Compiler:

D.M. Mason

Methodology:

The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].

Sample Information:
  1. VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
  2. DDR pro analysis grade by DDR Standard TGL 5021.
  3. Double distilled.
Measurement Errors:

Ambient temperature: Not given.

Methodology Citation

1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.

System Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Sodium fluoride, $\ce{ NaF }$; [7681-49-4] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $C_{2}$ (mol/dm3) α ($\pu{cm3(g) cm-3(l) atm-1}$) $S$
288.15150 0.990a-
288.15150.5 0.800a0.800b
293.15200 0.860a-
293.15200.5 0.674a0.6745b
298.15250 0.758a-
298.15250.5 0.582a0.583b
303.15300 0.671a-
303.15300.5 0.488a0.489b
308.15350 0.605a-
308.15350.5 0.415a0.417b
313.15400 0.546a-
313.15400.5 0.356a0.3575b
318.15450 0.482a-
318.15450.5 0.304a0.306b
323.15500 0.436a-
323.15500.5 0.260a0.262b
328.15550 0.392a-
328.15550.5 0.228a0.230b
333.15600 0.372a-
333.15600.5 0.202a0.2043b

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

(b) S= Kuenen coefficient [cm3 (STP) g-1(H2O) atm-1].

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