SDS Volume (2634)

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Original Measurements

Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.

Variables:

Room Temp: 288.15 - 333.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol dm-3 = 0 - 2 g/L

Prepared by:

D.M. Mason

Method/Apparatus/Procedure:

The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].

Source and Purity of Materials:
  1. VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
  2. DDR pro analysis grade by DDR Standard TGL 5021.
  3. Double distilled.
Estimated Errors:

Ambient temperature: Not given.

References

1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.

Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Lithium sulfate, $\ce{ Li2SO4 }$; [10377-48-7] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $C_{2}$ (mol/dm3) α ($\pu{cm3(g) cm-3(l) atm-1}$) $S$
288.15150 0.990-
288.15150.25 0.8110.8155
288.15150.5 0.7040.7115
288.15151 0.5200.5325
288.15152 0.2840.299
293.15200 0.860-
293.15200.25 0.6910.6955
293.15200.5 0.5980.605
293.15201 0.4370.448
293.15202 0.2370.250
298.15250 0.758-
298.15250.25 0.5940.5983
298.15250.5 0.5190.525
298.15251 0.3610.371
298.15252 0.2030.2142
303.15300 0.670-
303.15300.25 0.5180.523
303.15300.5 0.4460.452
303.15301 0.3020.3105
303.15302 0.1810.191
308.15350 0.605-
308.15350.25 0.4500.4550
308.15350.5 0.3850.391
308.15351 0.2610.268
308.15352 0.1600.169
313.15400 0.546-
313.15400.25 0.3910.3953
313.15400.5 0.3380.344
313.15401 0.2330.2395
313.15402 0.1400.1485
318.15450 0.482-
318.15450.5 0.2980.3035
318.15451 0.2070.2133
318.15452 0.1260.1338
323.15500 0.436-
323.15500.5 0.2660.271
323.15501 0.1860.192
323.15502 0.1130.1195
328.15550 0.392-
328.15550.5 0.2340.239
328.15551 0.1060.176
328.15552 0.1060.113
333.15600 0.372-
333.15600.5 0.2080.2125
333.15601 0.1510.156
333.15602 0.09870.105

(b) S = Kuenen coefficient [cm3 (STP) g-1 (H2O) atm-1].

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

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