SDS Volume

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Source Publication

Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.

Conditions:

Room Temp: 288.15 - 333.15 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$
Amount concentration (2): C2/mol dm-3 = 0 - 2 g/L

Compiler:

D.M. Mason

Methodology:

The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].

Sample Information:
  1. VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
  2. DDR pro analysis grade by DDR Standard TGL 5021.
  3. Double distilled.
Measurement Errors:

Ambient temperature: Not given.

Methodology Citation

1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.

System Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Lithium sulfate, $\ce{ Li2SO4 }$; [10377-48-7] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $C_{2}$ (mol/dm3) α ($\pu{cm3(g) cm-3(l) atm-1}$) $S$
288.15150 0.990a-
288.15150.25 0.811a0.8155b
288.15150.5 0.704a0.7115b
288.15151 0.520a0.5325b
288.15152 0.284a0.299b
293.15200 0.860a-
293.15200.25 0.691a0.6955b
293.15200.5 0.598a0.605b
293.15201 0.437a0.448b
293.15202 0.237a0.250b
298.15250 0.758a-
298.15250.25 0.594a0.5983b
298.15250.5 0.519a0.525b
298.15251 0.361a0.371b
298.15252 0.203a0.2142b
303.15300 0.670a-
303.15300.25 0.518a0.523b
303.15300.5 0.446a0.452b
303.15301 0.302a0.3105b
303.15302 0.181a0.191b
308.15350 0.605a-
308.15350.25 0.450a0.4550b
308.15350.5 0.385a0.391b
308.15351 0.261a0.268b
308.15352 0.160a0.169b
313.15400 0.546a-
313.15400.25 0.391a0.3953b
313.15400.5 0.338a0.344b
313.15401 0.233a0.2395b
313.15402 0.140a0.1485b
318.15450 0.482a-
318.15450.5 0.298a0.3035b
318.15451 0.207a0.2133b
318.15452 0.126a0.1338b
323.15500 0.436a-
323.15500.5 0.266a0.271b
323.15501 0.186a0.192b
323.15502 0.113a0.1195b
328.15550 0.392a-
328.15550.5 0.234a0.239b
328.15551 0.106a0.176b
328.15552 0.106a0.113b
333.15600 0.372a-
333.15600.5 0.208a0.2125b
333.15601 0.151a0.156b
333.15602 0.0987a0.105b

(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].

(b) S = Kuenen coefficient [cm3 (STP) g-1 (H2O) atm-1].

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