SDS Volume
Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None
Source Publication
Gerecke, J.; Diss. Dr. rer. Nat. 1969, Hochsch. "Carl Schorlemmer", Leuna-Merseburg, DDR.
Conditions:
Room Temp:
288.15 - 333.15
$\pu{K}$
Pressure:
101.325
$\pu{kPa}$
Amount concentration (2):
C2/mol dm-3 = 0 - 2
g/L
Compiler:
Methodology:
The principle of the Ostwald method was used in which a measured volume of gas-free liquid is stirred in the presence of the gas, and its decrease in volume is measured in a burette over mercury. The volume of liquid was measured at the experimental temperature. For calculation of the Kuenen coefficient, the density of the solution was obtained from Landolt-Börnstein extant 1969. The molar concentration of salt in the liquid was standardized at 20 °C. These data are analyzed and discussed further in [1].
Sample Information:
- VEB Leuna Works; 99.8 vol%; the impurity was mostly water (author).
- DDR pro analysis grade by DDR Standard TGL 5021.
- Double distilled.
Measurement Errors:
Ambient temperature: Not given.
Methodology Citation
1 Gerecke, J.; Bittrich, H. J.; Wiss. Z. Tech. Hochsch. Chem. 'Carl Schorlemmer' Leuna-Merseburg 1971, 13(2), 115-22.
System Components:
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Lithium sulfate, $\ce{ Li2SO4 }$; [10377-48-7] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ ($\pu{K}$) | $T$ (°C) | $C_{2}$ (mol/dm3) | α ($\pu{cm3(g) cm-3(l) atm-1}$) | $S$ |
|---|---|---|---|---|
| 288.15 | 15 | 0 | 0.990a | - |
| 288.15 | 15 | 0.25 | 0.811a | 0.8155b |
| 288.15 | 15 | 0.5 | 0.704a | 0.7115b |
| 288.15 | 15 | 1 | 0.520a | 0.5325b |
| 288.15 | 15 | 2 | 0.284a | 0.299b |
| 293.15 | 20 | 0 | 0.860a | - |
| 293.15 | 20 | 0.25 | 0.691a | 0.6955b |
| 293.15 | 20 | 0.5 | 0.598a | 0.605b |
| 293.15 | 20 | 1 | 0.437a | 0.448b |
| 293.15 | 20 | 2 | 0.237a | 0.250b |
| 298.15 | 25 | 0 | 0.758a | - |
| 298.15 | 25 | 0.25 | 0.594a | 0.5983b |
| 298.15 | 25 | 0.5 | 0.519a | 0.525b |
| 298.15 | 25 | 1 | 0.361a | 0.371b |
| 298.15 | 25 | 2 | 0.203a | 0.2142b |
| 303.15 | 30 | 0 | 0.670a | - |
| 303.15 | 30 | 0.25 | 0.518a | 0.523b |
| 303.15 | 30 | 0.5 | 0.446a | 0.452b |
| 303.15 | 30 | 1 | 0.302a | 0.3105b |
| 303.15 | 30 | 2 | 0.181a | 0.191b |
| 308.15 | 35 | 0 | 0.605a | - |
| 308.15 | 35 | 0.25 | 0.450a | 0.4550b |
| 308.15 | 35 | 0.5 | 0.385a | 0.391b |
| 308.15 | 35 | 1 | 0.261a | 0.268b |
| 308.15 | 35 | 2 | 0.160a | 0.169b |
| 313.15 | 40 | 0 | 0.546a | - |
| 313.15 | 40 | 0.25 | 0.391a | 0.3953b |
| 313.15 | 40 | 0.5 | 0.338a | 0.344b |
| 313.15 | 40 | 1 | 0.233a | 0.2395b |
| 313.15 | 40 | 2 | 0.140a | 0.1485b |
| 318.15 | 45 | 0 | 0.482a | - |
| 318.15 | 45 | 0.5 | 0.298a | 0.3035b |
| 318.15 | 45 | 1 | 0.207a | 0.2133b |
| 318.15 | 45 | 2 | 0.126a | 0.1338b |
| 323.15 | 50 | 0 | 0.436a | - |
| 323.15 | 50 | 0.5 | 0.266a | 0.271b |
| 323.15 | 50 | 1 | 0.186a | 0.192b |
| 323.15 | 50 | 2 | 0.113a | 0.1195b |
| 328.15 | 55 | 0 | 0.392a | - |
| 328.15 | 55 | 0.5 | 0.234a | 0.239b |
| 328.15 | 55 | 1 | 0.106a | 0.176b |
| 328.15 | 55 | 2 | 0.106a | 0.113b |
| 333.15 | 60 | 0 | 0.372a | - |
| 333.15 | 60 | 0.5 | 0.208a | 0.2125b |
| 333.15 | 60 | 1 | 0.151a | 0.156b |
| 333.15 | 60 | 2 | 0.0987a | 0.105b |
(a) α = Bunsen coefficient [cm3 (STP) cm-3 atm-1].
(b) S = Kuenen coefficient [cm3 (STP) g-1 (H2O) atm-1].


