SDS Volume

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Source Publication

Eremina, A. O.; Efanov, L. N.; Sorokina, N. A.; Russ. J. Phys. Chem. 1989, 63, 1361-63.

Conditions:

Room Temp: 298.15 and 313.15 $\pu{K}$
Pressure: 0.1 $\pu{MPa}$
Amount concentration (2): 103C2/mol L-1 = 0 - 50 g/L

Compiler:

Yu.P. Yampol'skii

Methodology:

Attainment of the equilibrium was checked by the constancy of $\ce{CO2}$ content in 3-5 subsequent samples of gas after saturation of the solution. The concentration of carbon dioxide was determined by titration. Detailed description of the technique is given in [1].

Sample Information:
  1. Source not given. Before contacting with water solutions $\ce{CO2}$ was allowed to pass through the vessels with $\ce{NaHCO3}$, glass beads, glass wool, and distilled water.
  2. Nothing specified.
  3. Distilled.
Measurement Errors:

Ambient temperature: δT/K = ±0.05
Mass concentration (m/v) (1): δc1/c1 = ±0.06-0.2%

Methodology Citation

1 Burmakina, G. V.; Efanov, L. N.; Shnet, M. A.; Russ. J. Phys. Chem. 1982, 56, 705-7.

System Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Barium chloride, $\ce{ BaCl2 }$; [10361-37-2] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $C_{2}$ (mol/L) $C_{1}$ (g/L)
298.150b 0.03390c
298.152.5 x 10-3b 0.03325c
298.155 x 10-3b 0.03283c
298.157.5 x 10-3b 0.03250c
298.150.010b 0.0322c
298.150.0125b 0.03277c
298.150.015b 0.03316c
298.150.020b 0.03294c
298.150.025b 0.03275c
298.150.050b 0.03175c
313.150b 0.02269c
313.152.5 x 10-3b 0.02223c
313.155 x 10-3b 0.02186c
313.157.5 x 10-3b 0.02160c
313.150.010b 0.02145c
313.150.0125b 0.02185c
313.150.015b 0.02222c
313.150.020b 0.02218c
313.150.025b 0.02211c
313.150.050b 0.02176c

(a) Data taken from a graph by compiler.

(b) c2 = concentration of BaCl2

(c) c1 = solubility of CO2

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