Components:

(1) Carbon dioxide, CO2; [124-38-9] NIST WebBook
(2) Calcium nitrate, Ca(NO3)2; [10124-37-5] NIST WebBook
(3) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

Yasunishi, A.; Yoshida, F.; J. Chem. Eng. Data 1979, 24, 11-14.

Variables:

Ambient temperature: 298.15 K
Pressure: 101.325 kPa
Amount concentration (2): C2/mol L-1 = 0 - 3.581

Prepared by:

C.L. Young

Method/Apparatus/Procedure:

Volumetric apparatus with multibulb buret and magnetic stirrer. Amount of solution and gas absorbed determined volumetrically. Density and composition of solution determined after absorption. Details in Ref. 1.

Source and Purity of Materials:
  1. (2,3) Guaranteed reagent, solution degassed by boiling.
  2. High purity grade sample, purity 99.96 mole%.
Estimated Errors:

Ambient temperature: δT/K = ±0.05
Mass concentration (m/v) (1): δL = ±1%

References

1 Tokunaga, J.; J. Chem. Eng. Data 1975, 20, 41.

Experimental Values:
Note: P = 1 atm = 101.325 kPa = 1.01325 bar
T (K) C2 (mol/L) L
298.15 0.0 8.264 x 10-1
298.15 2.32 x 10-1 7.630 x 10-1
298.15 5.10 x 10-1 7.027 x 10-1
298.15 8.01 x 10-1 6.363 x 10-1
298.15 1.158 5.584 x 10-1
298.15 1.476 5.014 x 10-1
298.15 1.788 4.460 x 10-1
298.15 2.062 4.067 x 10-1
298.15 2.504 3.430 x 10-1
298.15 3.581 2.370 x 10-1

(a) L = Ostwald coefficient (cm3 cm-3)

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