SDS Volume (2610)

Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None

Original Measurements

Malinin, S. D.; Savelyeva, N. I.; Geochem. Int. 1972, 9, 410-8.

Variables:

Room Temp: 293.15 - 353.15 $\pu{K}$
Pressure: 47.95 bar $\pu{bar}$
Amount concentration (2): C2/mol L-1 = 0 - 3.854 g/L

Prepared by:

C.L. Young

Method/Apparatus/Procedure:

Flow system with about 0.25 L of solution in 0.5 L stainless steel cell. After equilibrium established, liquid sampled and carbon dioxide absorbed in potassium hydroxide. Gain in weight of absorption train used to estimate amount of carbon dioxide. Details in source.

Source and Purity of Materials:
  1. GOST 8050-64 sample.
  2. Analytical reagent grade sample.
  3. No details given.
Estimated Errors:

Ambient temperature: δT/K = ±0.1 (estimated by the compiler)
Mass concentration (m/v) (1): δC1, δS1 = ±0.5% (estimated by the compiler)
Pressure: δP/bar = ±0.1 (estimated by the compiler)

Components:
  1. Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
  2. Calcium chloride, $\ce{ CaCl2 }$; [10043-52-4] NIST WebBook
  3. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $C_{2}$ (mol/L) $P$ ($\pu{bar}$) $S$ $C_{1}$ (g/kg)
293.150.00 47.9552.8452.84
293.150.437 47.9552.8441.37
293.150.437 47.9552.8442.20
293.150.879 47.9552.8433.59
293.151.349 47.9552.8426.80
293.151.349 47.9552.8426.71
293.152.341 47.9552.8416.84
293.152.341 47.9552.8416.81
293.153.443 47.9552.8410.49
293.153.443 47.9532.8610.47
323.150.00 47.9527.6332.86
323.150.437 47.9526.3326.39
323.150.5531 47.9526.3324.84
323.150.5531 47.9519.6824.82
323.151.349 47.9516.0117.14
323.151.935 47.9516.0113.19
323.151.935 47.9513.9613.19
323.152.354 47.9513.9611.07
353.150.00 47.9523.9223.92
353.150.1554 47.9522.4622.01
353.150.1554 47.9522.4622.15
353.150.8766 47.9516.8615.33
353.150.8766 47.9516.8615.36
353.151.173 47.9515.3713.84
353.151.173 47.9515.3730.60
353.151.283 47.9514.7012.88
353.151.283 47.9514.7012.68
353.152.099 47.9511.169.05
353.153.854 47.956.694.58

(b) Solubility of CO2: S1 = m1 (in grams) / 1 kg of water

(a) Solubility of CO2: C1 = m1 (in grams) / 1 kg of solution

(+) Equilibrium state approached from supersaturation

Download Data   link to XML output link to JSON output link to JSON-LD output