SDS Volume (2605)
Volume 62. Carbon Dioxide in Water and Aqueous Electrolyte Solutions, p None
Original Measurements
Yasunishi, A.; Yoshida, F.; J. Chem. Eng. Data 1979, 24, 11-14.
Variables:
Room Temp:
298.15
$\pu{K}$
Pressure:
101.325
$\pu{kPa}$
Amount concentration (2):
C2/mol L-1 = 0 - 3.372
g/L
Prepared by:
Method/Apparatus/Procedure:
Volumetric apparatus with multibulb buret and magnetic stirrer. Amount of solution and gas absorbed determined volumetrically. Density and composition of solution determined after absorption. Details in [1].
Source and Purity of Materials:
- High purity grade sample, purity 99.96 mole%.
- (2,3) Guaranteed reagent, solution degassed by boiling.
Estimated Errors:
Ambient temperature: δT/K = ±0.05
Mass concentration (m/v) (1): δL = ±1%
References
Components:
- Carbon dioxide, $\ce{ CO2 }$; [124-38-9] NIST WebBook
- Magnesium nitrate, $\ce{ Mg(NO3)2 }$; [10377-60-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
P = 1 atm = 101.325 kPa = 1.01325 bar
| $T$ ($\pu{K}$) | $C_{2}$ (mol/L) | $L$ |
|---|---|---|
| 298.15 | 0 | 0.8264 |
| 298.15 | 0.203 | 0.7771 |
| 298.15 | 0.364 | 0.7435 |
| 298.15 | 0.415 | 0.7328 |
| 298.15 | 0.636 | 0.6873 |
| 298.15 | 1.003 | 0.6129 |
| 298.15 | 1.007 | 0.6112 |
| 298.15 | 1.076 | 0.5975 |
| 298.15 | 1.158 | 0.5805 |
| 298.15 | 1.170 | 0.5765 |
| 298.15 | 1.350 | 0.5463 |
| 298.15 | 1.746 | 0.4801 |
| 298.15 | 1.925 | 0.4508 |
| 298.15 | 2.186 | 0.4186 |
| 298.15 | 2.587 | 0.3656 |
| 298.15 | 2.930 | 0.3253 |
| 298.15 | 3.372 | 0.2796 |
(a) L = Ostwald coefficient [cm3 cm-3]
