SDS Volume
Volume 60. Halogenated Methanes with Water, p None
Source Publication
Svetlanov, E. B.; Velichko, S. M.; Levinskii, M. I.; Treger, Yu. A.; Flid, R. M.; Russ. J. Phys. Chem. 1971, 45, 488-90.
Conditions:
Room Temp:
288 - 333
$\pu{K}$
Concentration
Compiler:
Methodology:
The dynamic method was used for the determination of solubility. It involved the saturation of nitrogen with terachloromethane vapor which was then bubbled through a thermostatically controlled flask filled with a definite volume of the aqueous solution. After 2 - 3 hours the solution became saturated and samples were taken periodically [1]. The concentration of tetrachloromethane in the aqueous solution was determined by gas chromatography. On average 3 - 5 measurements were taken at each temperature.
Sample Information:
- Source and purity not given.
- Source and purity not given.
- Distilled (compiler)
Measurement Errors:
Ambient temperature: ±0.05 K.
Mass concentration (m/v) (1): ±15%.
Methodology Citation
1 Treger, Yu. A.; Flid, R. M.; Spektor, S. S.; Russ. J. Phys. Chem. 38. 253 (1964)
System Components:
- Tetrachloromethane, $\ce{ CCl4 }$; [56-23-5] NIST WebBook
- Hydrogen chloride, $\ce{ HCl }$; [7647-01-0] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | w1 | 100w2 | 100w1 a | $x_{1}$ a |
|---|---|---|---|---|
| 15 | 1.00 x 10-3 | 1E+1 | 0.100 | 1.235 x 10-4 |
| 30 | 5.5 x 10-4 | 1E+1 | 0.055 | 6.79 x 10-5 |
| 45 | 3.0 x 10-4 | 1E+1 | 0.030 | 3.70 x 10-5 |
| 60 | 1.8 x 10-4 | 1E+1 | 0.018 | 2.22 x 10-5 |
| 15 | 1.25 x 10-3 | 2E+1 | 0.125 | 1.631 x 10-4 |
| 30 | 7.4 x 10-4 | 2E+1 | 0.074 | 9.65 x 10-5 |
| 45 | 4.0 x 10-4 | 2E+1 | 0.040 | 5.21 x 10-5 |
| 60 | 2.3 x 10-4 | 2E+1 | 0.023 | 3.00 x 10-5 |
