SDS Volume (2499)
Volume 60. Halogenated Methanes with Water, p None
Original Measurements
Staverman, A. J.; Recl. Trav. Chim. Pays-Bas 1941, 60, 836-41.
Variables:
Room Temp: 273 - 303 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
Tetrachloromethane was shaken with water for about 12 hours in a liquid paraffin thermostat bath. The water content of the organic phase was determined by the Karl Fischer titration method. All measurements were done in duplicates. The results were averages of two measurements at each temperature. A full description of the method used is given in a Ph.D. thesis [1].
Source and Purity of Materials:
- Distilled.
- Source and purity not given.
Estimated Errors:
Ambient temperature: ±0.5 K (compiled).
Mass concentration (m/v) (1): Not specified.
References
1 Staverman, A. J.; Ph.D. Dissertation, University of Leiden, Leiden, Belgium, 1938.
Components:
- Tetrachloromethane, $\ce{ CCl4 }$; [56-23-5] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | w1 | $x_{1}$ | $mol_{1}/\pu{100 g}$ (mol/g) |
|---|---|---|---|
| 0 | 5.0 x 10-5 | 4.28 x 10-4 | 2.77 x 10-6 |
| 25 | 1.16 x 10-4 | 9.91 x 10-4 | 6.44 x 10-6 |
| 30 | 1.58 x 10-4 | 1.350 x 10-3 | 8.77 x 10-6 |
