SDS Volume

Volume 60. Halogenated Methanes with Water, p None

Source Publication

Gross, P. M.; Saylor, J. H.; J. Am. Chem. Soc. 1931, 53, 1744-51.

Conditions:

Room Temp: 303 $\pu{K}$

Compiler:

A.L. Horvath

Methodology:

An excess of diiodomethane in 500 g water was shaken for 12 hours in a thermostat bath. Samples were then withdrawn and read against water in an interferometer made by Zeiss [1]. A detailed description of the complete method and procedure is given in a Ph.D. thesis [2].

Sample Information:

1. Eastman Kodak Co., shaken with $\ce{Na2S2O3}$ solution. washed with distilled water, dried, and fractionally frozen twice before use.
2. distilled.

Measurement Errors:

Ambient temperature: ±0.02 K.
Mass concentration (m/v) (1): ±2.0%.

Methodology Citations

¹ Gross, P. M.; J. Am. Chem. Soc. 1929, 51, 2362-6.
² Saylor, J. H.; Ph.D. Dissertation, Duke University, Durham, NC, 1930.