SDS Volume (2400)
Volume 60. Halogenated Methanes with Water, p None
Original Measurements
Vogel, A. I.; rev. by Furniss, B. S.; et al. Vogel's Textbook of Practical Organic Chemistry, 5th ed. (Longman, London, 1989), p. 1442.
Variables:
Room Temp: 293 $\pu{K}$
Prepared by:
Method/Apparatus/Procedure:
The solubility determination was done in small test tubes (e. g., 100 x 12 mm) to permit vigorous shaking of the trichloromethane and water mixture. During the experiment, 0.20 mL trichloromethane was added to 3.0 mL of water and shaken. The amount of trichloromethane in the water was analyzed by passing the sample through a chromatographic column.
Source and Purity of Materials:
- Commercial grade, dried over anhydrous $\ce{CaCl2}$ before use.
- distilled.
Estimated Errors:
Ambient temperature: ±1 K (compiler).
Mass concentration (m/v) (1): Not specified.
Components:
- Trichloromethane, $\ce{ CHCl3 }$; [67-66-3] NIST WebBook
- Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
| $T$ (°C) | 100w1 | $x_{1}$ | $mol_{1}/\pu{100 g}$ (mol/g) |
|---|---|---|---|
| 20.0 | 0.82 | 1.25 x 10-3 | 6.87 x 10-5 |
