SDS Volume (2377)

Volume 60. Halogenated Methanes with Water, p None

Original Measurements

Hutchinson, T. C.; Hellebust, J. A.; Tam, D.; Mackay, D.; Mascarenhas, R. A.; Shiu, W. Y.; 'Hydrocarbons and Halogenated Hydrocarbons in the Aquatic Environment' Plenum Press, 1980, p. 577-586.

Variables:

Room Temp: 298 $\pu{K}$

Prepared by:

A.L. Horvath

Method/Apparatus/Procedure:

An excess quantity of trichloromethane was added to water and stirred vigorously for 24 hours. After settling at 25 °C for 48 hours, the solution was extracted with cyclohexane. The samples were analyzed using an Aminco-Bowman spectrophotofluorometer. A detailed description of the method has been reported elsewhere [1].

Source and Purity of Materials:
  1. Aldrich Chemicals, highest grade, used as received.
  2. Double distilled.
Estimated Errors:

Ambient temperature: ±0.2 K (compiler).
Mass concentration (m/v) (1): Not specified.

References

1 Mackay, D.; Shiu, W. Y.; J. Chem. Eng. Data. 1977, 22, 399-402.

Components:
  1. Trichloromethane, $\ce{ CHCl3 }$; [67-66-3] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ (°C) ρ (g/L) 100w1 $x_{1}$
257.95 0.79731.21 x 10-3

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